MCTP Maryland Collaborative for Teacher Preparation Molecular Modeling with "ball-and-stick" model kits Thomas C. O'Haver Department of Chemistry and Biochemistry University of Maryland College Park, MD 20742 (301) 4051831 to2@umail.umd.edu NSF Cooperative Agreement No. DUE 9255745 ------------------------------------------------------------------------ Chemistry 121/122 Name________________________________ Molecular Modeling with "ball-and-stick" model kits For this experiment you will work in pairs. Pick a partner and unpack your model kit. 1. Why do you think the different types of atoms are given different colors? Are these colors the real colors of these atoms, or just arbitrary colors? 2. Locate on the periodic table in your textbook all the atom types included in the kit. 3. How many holes (for bonds) are there in these atoms? H hydrogen _____ C carbon _____ O oxygen _____ Cl chlorine _____ Br bromine _____ 4. Construct models for the diatomic molecules hydrogen (H2), chlorine (Cl2), and hydrogen chloride (HCl). What does the bond between the two atoms represent; that is, what is the bond actually composed of? 5. Construct a model for water (H2O) and compare it to the "dot structures" on page 34 of your textbook. Is your water model actually straight as suggested by the pictures on page 34? 6. What is the "octet rule" and how does it explain the tendency of oxygen to form two bonds, whereas chlorine, for example, forms only one bond? 7. Construct models for methane (CH4) and for chloroform (CHCl3). What shape is formed by the vertices of the molecule? 8. Construct models for ethane (C2H6), and propane (C3H8). Is there any other way to construct these molecules? 9. Construct a model for butane (C4H10). Can you find more than one way to construct a molecule with this formula? How many? 10. Ethanol is C2H6O. Try to construct that molecule. Can you find more than one way to construct it? 10. Some molecules contain so-called "double bonds". Build models for diatomic oxygen and for carbon dioxide. How many double bonds do these molecules have? 11. If you wanted to make a model for Freon 11 (page 48), what element is missing from your kit? What element could you substitute, that makes the same number of bonds as the missing element? 12. Octane (found in gasoline) has 8 carbons and is one of the family of hydrocarbons such as methane, ethane, butane, and propane. What formula would you predict for octane? Bibliography 1. The Printice Hall Molecular Model Set for Organic Chemistry, 1994. 2. American Chemical Society, "Chemistry in Context: Applying Chemistry to Society", Wm. C. Brown Publishers, 1994.